Crystal Structure of [<i>N</i>-(9-Anthracenylmethyl)-1,3-propanediamine](2,2′-bipyridine)platinum(II) Chloride

Abstract

The crystal structure of [N-(9-anthracenylmethyl)-1,3-propanediamine](2,2′-bipyridine)platinum(II) chloride was determined by X-ray crystallography. The title complex crystallized in the monoclinic space group P21/c and Z = 4 with cell parameters a = 11.2466(7)Å, b = 17.3553(10)Å, c = 13.7027(9)Å, β = 100.501(2) , V = 2629.8(3)Å 3. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0271 and 0.0619, respectively, for all 5995 independent reflections. The intramolecular π-π stacking interaction was observed between the anthracene and the bipyridine. In the crystal packing structure, the intermolecular π-π stacking interaction was observed.