Crystal structure of (Z)-2-((adamantan-1-ylimino)methyl)-5-methoxyphenol, C₁₈H₂₃NO₂

Abstract

C18H23NO2, monoclinic, C2/c (no. 15), a = 21.057(3) Å, b = 6.5535(7) Å, c = 24.069(4) Å, β = 113.535(3)°, V = 2780.9(5) Å3, Z = 8, Rgt(F) = 0.0607 , wRref(F2) = 0.1204, T = 293(2) K.

Synthesis, Molecular Structure from the X-ray Diffraction Data of the Powder (1E,1'E)-1,1'-(1,4-Phenylene)Bis(N-(Adamantan-1-yl)methanimine)

“…Furthermore, compounds that contain azomethines are reactive intermediates for organic synthesis in different fields and have biological [7,8], anti-viral [9], anti-bacterial [10,11], and anti-fungal [12] effects, as well as inhibiting anti-microbial agents [13]. A search in the CCDC Database survey gave few results containing adamantan-1-ylaminomethylbenzene fragment or 1,4-di(aminomethyl)benzene fragment [14][15][16][17][18][19][20]. Structures similar to the title compound are absent in the database.…”

Crystal structure of (E)-2-(2-chloro-6-hydroxybenzylidene)hydrazine-1-carbothioamide, C8H8ClN3O4S

“…Thiosemicarbazones are a class of important Schiff-bases and have received considerable attention for many years because of their biological activities and coordination chemistry properties [3][4][5][6][7][8][9][10][11][12][13][14]. In order to search for new thiosemicarbazones, the title compound was synthesized and its crystal structure was determined.…”