Crystal structure of fac-hexacarbonylbisμ2-(3-carboxy-3′-carboxylato-2,2′-bipyridine)-κ3
 N,N′:O-dirhenium(I) tetrahydrate, C30H22N4O18Re2

Schutte‐Smith, Marietjie; Visser, Hendrik G.; Roodt, Andreas

doi:10.1515/ncrs-2013-8010

Cited by 3 publications

(1 citation statement)

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“…This allows a vast variety of ligand systems, containing various combinations of donor atoms, i.e. N, S, P or O, to be coordinated to the metal ISSN 2053ISSN -2296 # 2018 International Union of Crystallography atom (Schutte-Smith et al, 2016;Nkoe et al, 2016;Bernhardt & Lawrance, 2004).…”

Section: Introductionmentioning

confidence: 99%

Synthesis of Re^Itricarbonyl complexes with various sulfur- and oxygen-donating ligands: crystal structures of two Re^Idinuclear structures bridged by S atoms

et al. 2018

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The synthesis and characterization of two dinuclear complexes, namely fachexacarbonyl-1 3 C,2 3 C-(pyridine-1N)[-2,2 0 -sulfanediyldi(ethanethiolato)-1 2 S 1 ,S 3 :2 3 S 1 ,S 2 ,S 3 ]dirhenium(I), [Re 2 (C 4 H 8 S 3 )(C 5 H 5 N)(CO) 6 ], (1), and tetraethylammonium fac-tris(-2-methoxybenzenethiolato-2 S:S)bis[tricarbonylrhenium(I)], (C 8 H 20 N)[Re 2 (C 7 H 7 OS) 3 (CO) 6 ], (2), together with two mononuclear complexes, namely (2,2 0 -bithiophene-5-carboxylic acid-2 S,S 0 )bromidotricarbonylrhenium(I), (3), and bromidotricarbonyl(methyl benzo[b]thiophene-2-carboxylate-2 O,S)rhenium(I), (4), are reported. Crystals of (1) and (2) were characterized by X-ray diffraction. The crystal structure of (1) revealed two Re-S-Re bridges. The thioether S atom only bonds to one of the Re I metal centres, while the geometry of the second Re I metal centre is completed by a pyridine ligand. The structure of (2) is characterized by three S-atom bridges and an ReÁ Á ÁRe nonbonding distance of 3.4879 (5) Å , which is shorter than the distance found for (1) [3.7996 (6)/3.7963 (6) Å ], but still clearly a nonbonding distance. Complex (1) is stabilized by six intermolecular hydrogen-bond interactions and an OÁ Á ÁO interaction, while (2) is stabilized by two intermolecular hydrogen-bond interactions and two OÁ Á Á interactions.

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Section: Introductionmentioning

confidence: 99%

Synthesis of Re^Itricarbonyl complexes with various sulfur- and oxygen-donating ligands: crystal structures of two Re^Idinuclear structures bridged by S atoms

et al. 2018

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A potential novel and general route for bromide replacement in diimine ReI tricarbonyl complexes leading to carboxylates: The effect in luminescence

et al. 2022

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Polypyridyl coordinated rhenium(I) tricarbonyl complexes as model devices for cancer diagnosis and treatment

Moherane

Alexander²,

Schutte‐Smith³

et al. 2022

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Crystal structure of fac-hexacarbonylbisμ₂-(3-carboxy-3′-carboxylato-2,2′-bipyridine)-κ³ N,N′:O-dirhenium(I) tetrahydrate, C₃₀H₂₂N₄O₁₈Re₂

Abstract: C 30 H 22 N4O 18 Re 2 , monoclinic, P21/c (no. 14), a = 10.167 (7) CCDC no.: 1456702The crystal structure is shown in the gure. Tables 1-3 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters.

Cited by 3 publications

References 24 publications

Synthesis of Re^Itricarbonyl complexes with various sulfur- and oxygen-donating ligands: crystal structures of two Re^Idinuclear structures bridged by S atoms

Synthesis of Re^Itricarbonyl complexes with various sulfur- and oxygen-donating ligands: crystal structures of two Re^Idinuclear structures bridged by S atoms

A potential novel and general route for bromide replacement in diimine ReI tricarbonyl complexes leading to carboxylates: The effect in luminescence

Polypyridyl coordinated rhenium(I) tricarbonyl complexes as model devices for cancer diagnosis and treatment

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Crystal structure of fac-hexacarbonylbisμ2-(3-carboxy-3′-carboxylato-2,2′-bipyridine)-κ3 N,N′:O-dirhenium(I) tetrahydrate, C30H22N4O18Re2

Abstract: C 30 H 22 N4O 18 Re 2 , monoclinic, P21/c (no. 14), a = 10.167 (7) CCDC no.: 1456702The crystal structure is shown in the gure. Tables 1-3 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters.

Cited by 3 publications

References 24 publications

Synthesis of ReItricarbonyl complexes with various sulfur- and oxygen-donating ligands: crystal structures of two ReIdinuclear structures bridged by S atoms

Synthesis of ReItricarbonyl complexes with various sulfur- and oxygen-donating ligands: crystal structures of two ReIdinuclear structures bridged by S atoms

A potential novel and general route for bromide replacement in diimine ReI tricarbonyl complexes leading to carboxylates: The effect in luminescence

Polypyridyl coordinated rhenium(I) tricarbonyl complexes as model devices for cancer diagnosis and treatment

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Crystal structure of fac-hexacarbonylbisμ₂-(3-carboxy-3′-carboxylato-2,2′-bipyridine)-κ³ N,N′:O-dirhenium(I) tetrahydrate, C₃₀H₂₂N₄O₁₈Re₂

Synthesis of Re^Itricarbonyl complexes with various sulfur- and oxygen-donating ligands: crystal structures of two Re^Idinuclear structures bridged by S atoms

Synthesis of Re^Itricarbonyl complexes with various sulfur- and oxygen-donating ligands: crystal structures of two Re^Idinuclear structures bridged by S atoms