Abstract:The title compound, C26H23BN2O2, was obtained as by product during synthetic attempts of a complexation reaction between the tripodal ligand H2L[N,N-bis(2-hydroxybenzyl)(pyridin-2-yl)methylamine] and manganese(III) acetate in the presence of NaBPh4. The isolatedB-phenyl dioxazaborocine contains an N→B dative bond with acisconformation. In the crystal, C—H...O hydrogen bonds define chains parallel to theb-axis direction. A comparative analysis with other structurally related derivatives is also included, togeth… Show more
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