Crystal structure of catena-poly[tetraaqua-(μ ₂-4,4′-bipyridine-k² N:N′)-zinc(II)] fumarate tetrahydrate, C₁₄H₂₆N₂O₁₂Zn

Abstract

CCDC no.: 1442536The crystal structure is shown in the gure, Tables 1-3 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters. Source of materialA mixture of fumaric acid (0.0116 g, 0.1 mmol), Zn(CH 3 COO) 2 (0.020 g, 0.1 mmol), 4,4′-bipyridine (0.016 g, 0.1 mmol), NaOH (0.2 M, 1.5 mL) and H 2 O (10 mL) was stirred for about 30 min. The resulting solution was sealed in a Te on-lined stainless autoclave and heated to 393 K for 3 days. The bottle was cooled to ambient temperature spontaneously. Colourless single crystals (about 84%, based on Zn input) were recovered by vacuum ltration, drying in air.