Crystal structure of dinitrato-κO-bis(tris((1H-benzo[d]imidazol-2-yl)methyl)amine-κ⁴ N,N′,N′′,N′′′)-(μ₂-cyclohexane-1,4-dicarboxylato-κ⁴ O,O′:O′′,O′′′)dimanganese(II) – methanol – water (1/6/2), C₆₂H₈₀Mn₂N₁₆O₁₈

Abstract

CCDC no.: 1561965The title complex is shown in the figure. Tables 1 and 2 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters. Source of materialTris(2-benzimidazolylmethyl)amine (ntb) was prepared according to the literature [3]. To a stirred methanol solution (20 mL) containing manganese(II) nitrate hexahydrate (0.057 g, 0.2 mmol) and ntb (0.08 g, 0.2 mmol), a methanol solution (10 mL) of 1,4-cyclohexanedicarboxylic acid (1,4-chdc, 0.017 g, 0.1 mmol) and triethylamine (0.022 g, 0.2 mmol) was added dropwise. After stirring for 2 hours, the