Crystal structure of diiodo(2,2′-bipyrimidine-k2N,N′)platinum(II), PtI2(C8H6N4)

Ha, Kwang

doi:10.1524/ncrs.2010.0289

Zeitschrift Für Kristallographie - New Crystal Structures

2010

DOI: 10.1524/ncrs.2010.0289

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Crystal structure of diiodo(2,2′-bipyrimidine-k2N,N′)platinum(II), PtI2(C8H6N4)

Kwang Ha¹

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Cited by 2 publications

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(2,2′-Bipyrimidine-κ²N¹,N^1′)bis(thiocyanato-κN)platinum(II)

2012

Acta Cryst E

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In the title complex, [Pt(NCS)2(C8H6N4)], the PtII ion is four-coordinated in a distorted square-planar environment defined by two pyrimidine N atoms derived from a chelating 2,2′-bipyrimidine (bpym) ligand and two mutually cis N atoms from two SCN− anions. The thiocyanate ligands are almost linear, displaying N—C—S bond angles of 178.6 (11) and 173.7 (11)°, and the N atoms are slightly bent coordinated to the Pt atom with Pt—N—C bond angles of 172.7 (9) and 160.4 (10)°. In the crystal, molecules are held together by C—H⋯S hydrogen bonds. Intramolecular C—H⋯N hydrogen bonds are also observed

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(2,2′-Bipyrimidine-κ²N¹,N^1′)bis(thiocyanato-κN)platinum(II)

2012

Acta Cryst E

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Crystal structure of cis-bis(2,2′-bipyrimidine-κ²N,N′)bis(thiocyanato-κN)nickel(II), C₁₈H₁₂N₁₀NiS₂

2016

Zeitschrift Für Kristallographie - New Crystal Structures

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CCDC no.: 1506237The crystal structure is shown in the gure. Tables 1 and 2 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters. Source of materialTo a solution of Ni(SCN) 2 ·4H 2 O (0.084 g, 0.34 mmol) in MeOH (10 mL) was added 2,2′-bipyrimidine (bpym; 0.108 g, 0.683 mmol) and stirred for 10 min at 50°C. The formed precipitate was separated by ltration, washed with MeOH and ether and dried at room temperature, to give a yellow powder (0.0747 g). Crystals were obtained by slow evaporation from an N,N-dimethylformamide solution at 60°C.

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Crystal structure of diiodo(2,2′-bipyrimidine-k2N,N′)platinum(II), PtI2(C8H6N4)

Cited by 2 publications

References 1 publication

(2,2′-Bipyrimidine-κ²N¹,N^1′)bis(thiocyanato-κN)platinum(II)

(2,2′-Bipyrimidine-κ²N¹,N^1′)bis(thiocyanato-κN)platinum(II)

Crystal structure of cis-bis(2,2′-bipyrimidine-κ²N,N′)bis(thiocyanato-κN)nickel(II), C₁₈H₁₂N₁₀NiS₂

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Crystal structure of diiodo(2,2′-bipyrimidine-k2N,N′)platinum(II), PtI2(C8H6N4)

Cited by 2 publications

References 1 publication

(2,2′-Bipyrimidine-κ2N1,N1′)bis(thiocyanato-κN)platinum(II)

(2,2′-Bipyrimidine-κ2N1,N1′)bis(thiocyanato-κN)platinum(II)

Crystal structure of cis-bis(2,2′-bipyrimidine-κ2N,N′)bis(thiocyanato-κN)nickel(II), C18H12N10NiS2

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(2,2′-Bipyrimidine-κ²N¹,N^1′)bis(thiocyanato-κN)platinum(II)

(2,2′-Bipyrimidine-κ²N¹,N^1′)bis(thiocyanato-κN)platinum(II)

Crystal structure of cis-bis(2,2′-bipyrimidine-κ²N,N′)bis(thiocyanato-κN)nickel(II), C₁₈H₁₂N₁₀NiS₂