Abstract:The crystal structure of [Co2Cl4(C17H18N2)2][CoCl2(C17H18N2)(H2O)] or [Co(L)Cl(μ-Cl)]2[Co(L)(Cl)2(OH2)], where L is the enantiopure bidentate ligand (−)-5,6-pinenebipyridine (C17H18N2), has been determined. Crystals suitable for X-ray structure analysis were obtained by slow evaporation of an ethanolic solution containing equimolar amounts of L and CoCl2·6H2O. The CoII cations all have a coordination number of five, and in each case the coordination polyhedron is a trigonal bipyramid. The Co—N bonds lengths ra… Show more
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