Crystal structure of chlorido-(η ⁵-pentamethylcyclopentadienyl)-((bis-pyrazol-1-yl)methane-κ² N,N′) rhodium(III) hexafluorophosphate. (C₁₇H₂₃ClN₄RhF₆P)

Abstract

C17H23ClN4RhF6P, monoclinic, P21/c (no. 14), a = 10.6954(2) Å, b = 15.3868(3) Å, c = 12.6130(2) Å, β = 90.5590(10)°, V = 2075.60(7) Å3, Z = 4, Rgt(F) = 0.0296, wRref(F2) = 0.0727, T = 100(2) K.

Crystal structure of chlorido-(η 5-pentamethylcyclopentadienyl)-(4-chloro-4-pyridyl-2,2′:6′,2′′-terpyridine-κ2N,N′) rhodium(III) hexaflourophosphate, C31H29Cl2F6N3PRh

“…The N-Rh-N angle is 76.80 (8)°and is in agreement with related complexes reported in the literature [5,7,[14][15][16]. The N-Rh-N bite angle is 84.36°which is similar to those reported for other Rh complexes with N-N-bidentate ligands [5,7,[14][15][16]. The Rh-N distances in the complex are 2.1082(2) and 2.192(2) Å and they are comparable to those previously reported in the literature [5,7,[14][15][16].…”

“…This gives the pseudo-octahedral piano-stool conformation around the rhodium centres in the complex. The N-Rh-N angle is 76.80 (8)°and is in agreement with related complexes reported in the literature [5,7,[14][15][16]. The N-Rh-N bite angle is 84.36°which is similar to those reported for other Rh complexes with N-N-bidentate ligands [5,7,[14][15][16].…”