Crystal structure of calcium cis(N)-bis(iminodiacetato)chromate(III) nonahydrate Ca[Cr(Ida)2]2·9H2O

Zabel, Manfred; Павловский, В. И.; Poznyak, A. L.

doi:10.1007/s10947-009-0090-3

Cited by 3 publications

(2 citation statements)

References 5 publications

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“…The coordinated N atoms are mutually trans (s-fac) arrangement. The facial configuration of (I) can be compared with the cis(ufac) geometry of K[Cr(ida)2]·3H2O [1], Ca[Cr(ida)2]2·9H2O [16] and Na[Cr(ida)2]·1.5H2O [2]. The Cr(III) ion is situated on a crystallographic center.…”

Section: Resultsmentioning

confidence: 99%

Crystal Structure and Hirshfeld Surface Analysis of Potassium sym-fac-Bis(N-methyliminodiacetato)chromate(III)

Moon¹,

Ryoo²,

Choi³

2018

Asian J. Chem.

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The structure of K[Cr(C5H7NO4)2] (C5H7NO4 is methyliminodiacetate; mida) was confirmed from synchrotron X-ray data at 173 K. The complex crystallized in the space group C2/c of the monoclinic system with four mononuclear formula units in a cell of dimensions a = 16.875(3), b = 6.3970(3), c = 13.784(3) Å and β = 113.81(3)°. The Cr(III) ion is located on a center of symmetry with one independent Cr-N bond length of 2.0740 (14) Å and two Cr-O bond lengths of 1.9547 (12) and 1.9661 (12) Å. The Cr(III) ion is coordinated by two N atoms and four O atoms of symmetrical-facial mida ligands, displaying a distorted octahedral geometry. Hirshfeld surface analysis with 2D fingerprint plots revealed that the O···H, H···H and O···K interactions are the main intermolecular interactions. The crystal structure is stabilized by the O···H, H···H and O···K interactions among potassium cation, H atoms and O atoms of carboxylate group from neighbouring mida groups.

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Section: Resultsmentioning

confidence: 99%

Crystal Structure and Hirshfeld Surface Analysis of Potassium sym-fac-Bis(N-methyliminodiacetato)chromate(III)

Moon¹,

Ryoo²,

Choi³

2018

Asian J. Chem.

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“…This is expected as the hard electron-pair acceptors iron(III) and chromium(III) prefer binding to the harder oxygen than to the softer nitrogen. Thirteen crystal structures containing chromium(III) iminodiacetate or alkyl-N-iminodiacetate complexes have been reported, Cr(R-N)(CH 2 COO) 2 − , R = H [10][11][12], R = CH 3 [13][14][15], R = CH(CH 3 ) 2 [16], R = C(CH 3 ) 3 [17], R = CH 2 CH 2 OH [18], R = CHCONH 2 [19,20] and R = CH 2 COOH [21]. In these complexes chromium(III) binds strongly to four oxygen atoms from the carboxylate groups, mean of 1.96 Å, and to two imine nitrogens at significantly longer bond distance, mean 2.09 Å, see Table S7 for details.…”

Section: Introductionmentioning

confidence: 99%

Complex Formation of Alkyl-N-iminodiacetic Acids and Hard Metal Ions in Aqueous Solution and Solid State

2020

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The calcium(II), iron(III) and chromium(III) alkyl-N-iminodiacetate systems have been studied in aqueous solution with respect to stability, acid–base properties and structure. The calcium(II) ion forms only one weak complex with methyl-N-iminodiacetic acid in water, K1 = 12.9 (2) mol–1⋅dm3, while iron(III) and chromium(III) form very stable complexes with alkyl-N-iminodiacetic acids. The calcium(II)–methyl-N-iminodiacetate complex is octahedral in the solid state with most probably water in the remaining positions giving a mean Ca–O bond distance of ca. 2.36 Å. The iron(III) alkyl-N-iminodiacetate complexes have low solubility due to a strong tendency to form polymeric structures. Depending on pH in the solution at their preparation, the degree of hydrolysis in the resulting compound(s) may differ. In the solid state, the polymeric iron(III) alkyl-N-iminodiacetate compounds seem to have the mean composition Fe2O(Cx-IDA)5; the mean Fe–O bond distances to the oxo group and the alkyl-N-iminodiacetate ligands are 1.92 and 2.02 Å, respectively. In these complexes the nitrogen atoms are bound at much longer bond distances, 0.1–0.2 Å, than the carboxylate oxygens. This distribution with short strong Fe–O bonds and much longer and weaker Fe–N bonds is also found in most other structurally characterized iron(III) carboxylated amine/polyamine complexes. The chromium(III) alkyl-N-iminodiacetate complexes are octahedral in both solution and solid state, and the low solubility of the solid compounds indicates a polymeric structure with the ligands bridging chromium(III) ions. Also, chromium(III) binds oxygen atoms in carboxylated amines at significantly shorter distance than the nitrogen stoms. The chromium(III) alkyl-N-iminodiacetate complexes display such slow kinetics at titration with strong base that the back-titration with strong acid shows completely different acid–base properties, thus the acid–base reactions are irreversible.

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Synthesis, Crystal Structure, and Hirshfeld Surface Analysis of Rubidium trans-Bis(N-methyliminodiacetato)chromate(III)

Moon

Choi

2019

Crystallogr. Rep.

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Crystal structure of calcium cis(N)-bis(iminodiacetato)chromate(III) nonahydrate Ca[Cr(Ida)2]2·9H2O

Cited by 3 publications

References 5 publications

Crystal Structure and Hirshfeld Surface Analysis of Potassium sym-fac-Bis(N-methyliminodiacetato)chromate(III)

Crystal Structure and Hirshfeld Surface Analysis of Potassium sym-fac-Bis(N-methyliminodiacetato)chromate(III)

Complex Formation of Alkyl-N-iminodiacetic Acids and Hard Metal Ions in Aqueous Solution and Solid State

Synthesis, Crystal Structure, and Hirshfeld Surface Analysis of Rubidium trans-Bis(N-methyliminodiacetato)chromate(III)

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