Crystal Structure of Cadmium(ii) Terephthalate—3,14-Dimethyl- 2,6,13,17-TETRAAZATRICYCLO[14,4,01.18,07 12]docosane Dihydrate

Herein we analyze the accessibility of the trigonal-prismatic geometry to metal complexes with different electron configurations, as well as the ability of several hexadentate ligands to favor that coordination polyhedron. Our study combines i) a structural database analysis of the occurrence of the prismatic geometry throughout the transition-metal series, ii) a qualitative molecular orbital analysis of the distortions expected for a trigonal-prismatic geometry, and iii) a computational study of complexes of several transition-metal ions with different hexadentate ligands. Also the tendency of specific electron configurations to present a cis bond-stretch Jahn-Teller distortion is analyzed.

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The Trigonal Prism in Coordination Chemistry

Cremades

Echeverría

Álvarez

2010

Chemistry A European J

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Template synthesis of a rare 14-membered macrocyclic complex using cadmium(II) ion as a collector

Dorjani

Mardani

Moeini

et al. 2022

J Incl Phenom Macrocycl Chem

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Supramolecular architecture of cadmium(II)–terephthalate complexes having a tridentate or tetradentate Schiff base as blocking coligand

et al. 2005

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Crystal Structure of Cadmium(ii) Terephthalate—3,14-Dimethyl- 2,6,13,17-TETRAAZATRICYCLO[14,4,01.18,07 12]docosane Dihydrate

Abstract: 6,13,4,0' 18 ,0 712 ]docosane exists as a dihydrated six-coordinated skew-trapezoidal bipyramidal compound.. The cadmium atom is chelated by the four nitrogen atoms of the macrocycle and by the two carboxyl oxygen atoms of the terephthalato dianion.

Cited by 5 publications

References 14 publications

The Trigonal Prism in Coordination Chemistry

The Trigonal Prism in Coordination Chemistry

Template synthesis of a rare 14-membered macrocyclic complex using cadmium(II) ion as a collector

Supramolecular architecture of cadmium(II)–terephthalate complexes having a tridentate or tetradentate Schiff base as blocking coligand

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