Crystal structure of [(C2H5)2NH2]2[Cd3Br8(CdBr2)]·H2O: An augmented ribbon structure

Zinc, cadmium and mercury

“…Unintentional isolation of two new cadmium tellurium(IV) oxychlorides, [Cd 2 (Te 6 O 13 )][Cd 2 Cl 6 ] and [Cd 7 Cl 8 (Te 7 O 17 )], has been achieved. 32 The crystal structure of [(C 2 H 5 ) 2 NH 2 ] 2 [Cd 3 Br 8 (CdBr 2 )] Á H 2 O has been solved, 33 while the crystal structure of a range of complexes of the form [TmBu t ]CdEAr (TmBu t = tris(2-mercapto-1-tert-butylimidazolyl)hydroborato, EAr = SPh, SePh, TePh) have been obtained and show that the Cd-EAr bond lengths correlate closely with the covalent radius of the chalcogen. 34 The 1D polymer {Cd 2 Cl 4 [Pt 9 (CO) 18 ] 2À } N has been prepared by reaction of [NBu 4 ] 2 [Pt 9 (CO) 18 ] with CdCl 2 and studied crystallographically.…”

Synthesis, X-ray single crystal structure, likelihood of occurrence of intermolecular contacts, spectroscopic investigation and DFT quantum chemical calculations of zwitterionic complex: 1-Ethylpiperaziniumtrichlorozincate (II)

“…These materials have recently attracted further interest due to their potentially interesting catalytic, thermal, magnetic and electrical properties. The polymeric halometallates with Zn(II) metal ion, which have been reported to exhibit a wide range of attractive properties, such as optical, photoluminescent, catalytic, and electrical properties [1][2][3][4][5][6][7][8][9][10], belong to this class of compounds. The Zn(II) metal is recognized to be essential for life, being present in several naturally occurring metalloenzymes.…”