Crystal structure of bis(η5-pentamethylcyclopentadienyl)(μ3-(oxymethylidin)-cyclo-(tricarbonylcobalt)(monocarbonylcobalt)-(μ2-η2-3-trimethylpropinyl)titan, C31H39Co2<O5Ti

Abstract

Source of material[Cp* 2Ti(CºC t Bu)] (76 mg, 0.19 mmol) and Co2(CO)8 (65 mg, 0.19 mmol) were dissolved in 5 ml hexane. After 2 days at room temperature the black-orange solution was kept at 195 K. Black crystals appeared which were filtrated and dried in vacuo to afford 123 mg (98%) of the title compound.