Crystal structure of bis(2-hydroxyethyl(phenyl)carbamodithioate)nickel(II), C₁₈H₂₀N₂NiO₂S₄

Abstract

C 18 H 20 N 2 NiO 2 S4, monoclinic, P21/n (no. 14), a = 7.6548(1) Å, CCDC no.: 1562893The structure of the title complex is shown in the figure. Tables 1 and 2 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters. Source of materialsIn a Schlenk tube containing a tetrahydrofuran (THF) solution (30 mL) of N-(2-hydroxyethyl)aniline (0.91 mL, 7.28 mmol) was added potassium hydroxide (0.41 g, 7.31 mmol), followed by addition of carbon disulfide (0.44 mL, 7.28 mmol). The reactants were stirred at room temperature for 30 min until a clear orange solution was formed. From the solution, the equivalent of 1.97 mmol of ligand was removed and dissolved in 15 mL of water. NiCl 2 ·6H 2 O (0.99 mmol) (molar