Crystal structure of bis(2,6-dihydroxymethyl)pyridine-κ³ N,O,O′)-bis(μ₂-6-chloropyridin-2-olato-κ³ N,O:O)-bis(6-chloropyridin-2-olato-κO)-bis(nitrato-κ² O,O′)digadolinium(III), C₃₄H₃₀Cl₄Gd₂N₈O₁₄

Crystal structure of diazido-dimethanolato-bis(μ2-2-(((3-oxidopropyl)imino)methyl)phenolato-κ4 O:O,O′,N)dimanganese(III), C22H28Mn2N8O6

“…Design and synthesis of polynuclear transition metal aggregates have attracted great interest not only because of their potential application in biology, catalysis and material science but also owing to their intriguing variety of architectures and topologies [3,4]. In this field, the manganese Schiff base complex is a fruitful subclass of transition metal compounds, which have been paid much attention on their bioinorganic and physical aspects such as to imitate the oxygen evolution center (OEC) in photosystem (PSII) and single-molecule magnets (SMMs) [5,6].…”