Crystal structure of bis(2-{1-[(E)-(4-fluorobenzyl)imino]ethyl}phenolato-κ²N,O)palladium(II)

Abstract

In the square planar [Pd(C15H13FNO)2] complex, weak C—H⋯O and π–π inter­actions play important roles in the mol­ecular self-assembly, resulting in the formation of two-dimensional mol­ecular sheets which are further stacked along the b axis.

Palladium complexes containing imino phenoxide ligands: synthesis, luminescence, and their use as catalysts for the ring-opening polymerization of rac-lactide

“…In this contribution, we report on the synthesis, structural characterization, photophysical, and catalysis studies of some square-planar Pd(II) complexes bearing imino phenoxide ligands with different structural modifications. Furthermore, although similar Pd(II) complexes have been prepared previously, to the best of our knowledge, the catalysis for the ROP of rac -LA using Pd(II) complexes containing the imino phenoxide backbone is still unreported [ 38 – 43 ].…”