Crystal structure of bis(1,3-phenylenedimethanaminium) bis(triiodide) tetraiodide – water (1/2) , C₈H₁₆I₅N₂O

Abstract

<jats:title>Abstract</jats:title><jats:p>C<jats:sub>8</jats:sub>H<jats:sub>16</jats:sub>I<jats:sub>5</jats:sub>N<jats:sub>2</jats:sub>O, monoclinic, <jats:italic>C</jats:italic>2/<jats:italic>c</jats:italic> (no. 15), <jats:italic>a</jats:italic> = 34.180(5) Å, <jats:italic>b</jats:italic> = 7.6817(3) Å, <jats:italic>c</jats:italic> = 21.421(3) Å, <jats:italic>β</jats:italic> = 137.93(3)°, <jats:italic>Z</jats:italic> = 8, <jats:italic>V</jats:italic> = 3768.7(16) Å<jats:sup>3</jats:sup>, R<jats:sub>gt</jats:sub>(<jats:italic>F</jats:italic>) = 0.0364, <jats:italic>wR</jats:italic><jats:sub>ref</jats:sub> = 0.0737, <jats:italic>T</jats:italic> = 290(2) K.</jats:p>

Antimicrobial Hexaaquacopper(II) Complexes with Novel Polyiodide Chains

“…But the secondary halogen bonds to I1 and I2 are with I ... I distances of 3.3780(6) Å for I1-I3 and 3.3781(7) Å I2-I3 significantly longer and obviously much weaker (Figure 4) [46][47][48][49]. The two weakly bonded iodine molecules are arranged around inversion centers (Wyckoff sites: 1c and 1g).…”

Supramolecular association of (1,4-phenylenedimethanaminium) bis(perchlorate) monohydrate: A combined experimental and theoretical study

“…A long-standing interest was devoted to the structural chemistry of diammonium cations type and to their hydrogen bonding schemes [1][2][3][4]. Here one of the Xylylenediamine derivatives which are well-known diamines that incorporates everalalluring biological and notably anti-microbial properties, will be the candidate for the organic counterpart.…”