2015
DOI: 10.1515/ncrs-2014-9090
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Crystal structure of benzylthiazolo[5,4-b]pyridin-2-yl-diazene, C13H10N4S

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“…The flexibility of flexible N-donor ligands can result not only in various conformations in coordination, but also in free rotation to meet the requirements of the coordination geometry of the metal ions in the assembly process. We have already shown that some N-based molecules serve as bridging ligands to coordinate metal ions [7][8][9]. In the title complex, there are one half of a Ni(II) ion, one 3,5-bpta ligand, and three water molecules in the asymmetric unit.…”
Section: Commentmentioning
confidence: 99%
“…The flexibility of flexible N-donor ligands can result not only in various conformations in coordination, but also in free rotation to meet the requirements of the coordination geometry of the metal ions in the assembly process. We have already shown that some N-based molecules serve as bridging ligands to coordinate metal ions [7][8][9]. In the title complex, there are one half of a Ni(II) ion, one 3,5-bpta ligand, and three water molecules in the asymmetric unit.…”
Section: Commentmentioning
confidence: 99%