Abstract:The orthophosphate BaNi2Fe(PO4)3 has been synthesized by a solid-state reaction route and characterized by single-crystal X-ray diffraction and energy-dispersive X-ray spectroscopy. The crystal structure comprises (100) sheets made up of [Ni2O10] dimers that are linked to two PO4 tetrahedra via common edges and vertices and of linear infinite [010] chains of corner-sharing [FeO6] octahedra and [PO4] tetrahedra. The linkage of the sheets and chains into a framework is accomplished through common vertices of PO4… Show more
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