Abstract:The title molecular salt, C15H21N2O+·ClO4
−, crystallizes with four cations (A, B, C and D) and four anions in the chiral unit cell (space group P21). The alkaloid was isolated from the aerial parts of Genista Hispanica collected in the Samarkand region of Uzbekistan. Each cation is protonated at the N atom that bridges the alkaloid rings C and D. In each cation, ring A is almost planar and ring B adops a sofa conformation with the methylene group bridging to the C ring as the flap. Rings C and D adopt chair… Show more
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