2013
DOI: 10.14233/ajchem.2013.14756
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Crystal Structure of an Unexpected Oxime-Type Polymer (C10H11BrNO)n

Abstract: Synthesis and crystal structure of oxime-type compounds and their complexes have been a hot topic in recent years 1. Oximes are easily prepared from the corresponding carbonyl compounds with hydroxylamine and its analogues are stable to hydrolysis compared with the corresponding imines. Thus, the electrophilicity of the imino carbon of oximes is lower and addition of nucleophiles to O-substituted oximes does not readily proceed 2. Because the oxime-type compounds are more stable to resist the metathesis of C=N… Show more

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