CRYSTAL STRUCTURE AND THERMAL STABILITY OF NEW IRON PHOSPHATES KMFe(PO4)2 (M = Ni, Mg, and Co)
Abstract:Three isostructural iron monophosphates KNiFe(PO 4) 2 (KNi), KMgFe(PO 4) 2 (KMg-LT, where LT means ″low-temperature stable phase″), and KCoFe(PO 4) 2 (KCo-LT) are synthesized and structurally characterized from X-ray diffraction data. They crystallize in the monoclinic system with the space group P2 1 /c. Their structures have in common a three-dimensional framework, built up by infinite zigzag chains of edge-sharing MO 6 (M = Ni, Mg or Co) octahedra, linked by FeO 5 and PO 4 polyhedra via vertices and edges t… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.