Crystal Structure and Catalytic Activity of A Novel Cd(II) Coordination Polymer Formed by Dicarboxylic Ligand

Abstract

A new Cd(II) coordination polymer, {[Cd3(L)2(DMF)2(H2O)2]·H2O}n (H2L = 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylic acid) was synthesized by one-pot synthesis method from 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylic acid, NaOH, DMF, and Cd(NO3)2·4H2O. Its structure was determined by elemental analysis and single crystal X-ray diffraction. Structural analysis shows that three Cd(II) ions are all six-coordinated with four oxygen atoms of four 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylate ligands and two O atoms from two DMF molecules (Cd1) or two oxygen atoms of two coordinated H2O molecules (Cd2 and Cd3) to form an octahedral coordination geometry. The Cd(II) coordination polymer displays a 1D chained structure by the bridging carboxylate groups from 1,3-bisbenzyl-2-imidazolidine-4,5-dicarboxylate ligands. The conversion of benzaldehyde is 90.9%, which is 40~50% higher than those of the other three aldehydes (4-methylbenzaldehyde, p-methoxybenzaldehyde and 3-chlorobenzaldehyde), so the Cd(II) coordination polymer catalyst shows better catalytic activity for the coupling reaction of benzaldehyde, phenylacetylene, and piperidine than the other three aldehydes. Copyright © 2018 BCREC Group. All rights reservedReceived: 25th April 2017; Revised: 11st September 2017; Accepted: 1st November 2017; Available online: 11st June 2018; Published regularly: 1st August 2018How to Cite: Ji, Z.X., Li, P.F. (2018). Crystal Structure and Catalytic Activity of A Novel Cd(II) Coordination Polymer Formed by Dicarboxylic Ligand. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (2): 220-226 (doi:10.9767/bcrec.13.2.1178.220-226)

Crystal Structures, Hirshfeld Surfaces, and Thermal Study of Isostructural Polymeric Ladders of La(III) and Sm(III) Coordination Compounds with 4,4’-Bipyridine and Dibromoacetates

“…These compounds find applications in many different areas of everyday life, industry, and science. Some of the examples are sensors and biosensors [ 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 ], electronic and optoelectronic devices [ 9 , 10 ], chemical catalysts, and photocatalysts [ 11 , 12 , 13 , 14 , 15 , 16 ]. Some coordination polymers can be used to remove harmful substances [ 17 , 18 , 19 , 20 ] or to capture and entrap other molecules [ 21 , 22 ].…”