Euhedral crystals of borcarite were found in vugs or fissures of crystal aggregates of nifontovite or pentahydroborite, which occur as irregularly shaped bodies in the crystalline limestone near the gehlenite spurrite skarns at the Fuka mine, Okayama Prefecture, Japan. Interfacial angles of the reference faces of borcarite crystals were measured for each zone using a one circle goniometer. The crystal basically comprises the {110}, {230}, {2 01}, {1 24} and {201} faces, but some crystals also have the {100}, {1 02}, {1 01}, {130}, {140}, {180}, {3 11} and {5 11} faces. Almost all the mineral is thin plate crystals along the zone [010]. The cleavage is perfect on {100}. Striation can be observed in the direction of [001]. This is the first description of a crystalline form of borcarite.