Crystal engineering strategy for quadratic nonlinear optics. Part II: Hg(IO3)2

Luminescence studies of Nd3+- and Yb3+-doped α-Y(IO3)3 and β-Y(IO3)3, transparent host matrix in the mid- and beginning of the far-infrared

“…Some of them are hydrated as In(IO 3 ) 3 Á 2H 2 O [22], In(IO 3 ) 3 Á 3H 2 O [23], Bi(IO 3 ) 3 Á 2H 2 O [24] and Yb(IO 3 ) 3 Á 2H 2 O [25]. Among the characterized anhydrous phases, many of them possess an acentric structure such as mercury iodate [26], cadmium iodate [27], isostructural phases M(IO 3 ) 2 (with M ¼ Mg, Mn, Co, Ni, Zn) [28] and M(IO 3 ) 3 (with M ¼ Ga, In) [29]. We demonstrated close structural relationships between these two last categories of metal iodates and a-LiIO 3 [29].…”

Synthesis and characterisation of Fe(IO3)3 nanosized powder

“…For some of them like Fe(IO 3 ) 3 , SHG coefficients can be as great as 100 times those of quartz [2,3,11]. The NLO properties are due to the electronic lone pair of the (IO 3 ) − group and recent works show a renewed interest in these iodate compounds [16][17][18][19][20][21][22][23]. For example, SHG coefficient of MMoO 3 (IO 3 ) with M = Rb or Cs and of Hg(IO 3 ), are reported to be respectively 400 and 300 times that of ␣-quartz [16,19].…”

Promising Material for Infrared Nonlinear Optics: NaI3O8 Salt Containing an Octaoxotriiodate(V) Anion Formed from Condensation of [IO3]− Ions

“…[1][2][3][4][5][6][7][8] In the 1970s, metal iodates had been extensively studied at Bell Laboratories for their NLO properties but also for their ferroelectric, piezoelectric, and pyroelectric properties. [9][10][11][12][13][14] Interest for iodate compounds resumed in the beginning of the 2000s.…”