Crystal and molecular structure of tetrachlorobis[<i>o</i>phenylenebis(dimethylarsino)]molybdenum(V) triiodide

Drew, M. G. B.; Egginton, G. M.; Wilkins, John D.

doi:10.1107/s0567740874006054

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1975

2021

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Cited by 15 publications

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“…In the cation the metal atom has crystallographically imposed dodecahedral symmetry as has been found in TiC14(diars)2 by Clark, Lewis, Nyholm, Pauling & Robertson (1961) and in [MoC14(diars)2] + by Drew, Egginton & Wilkins (1974). The anion is an octahedron.…”

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Tetrabromobis[o-phenylenebis(dimethylarsino)]tantalum(V) hexabromotantalate(V)

Drew¹,

Wolters²,

Wilkins³

1975

Acta Crystallogr Sect B

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“…2"583 (10) Ta(2)-Br(2) 2"487 (12) 2"765 (10) Ta(2)-Br (3) 2-490 (15) 74-9 (3) As(1)-C(1) 1.92 (8) 129.1 (2) As ( (4) 106 (7) 94.3 (34) C(3)--C(4)-C(4 ~) 127 (10) 111 (6) structure is that the diars ligand is well suited to the dodecahedron (Drew, Egginton & Wilkins, 1974).…”

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confidence: 99%