Crystal and molecular structure of silver perchlorate-adiponitrile (AgClO4.2NC(CH2)4CN)

Barnhart, David M.; Caughlan, Charles N.; Haque, M.K.

doi:10.1021/ic50082a045

Cited by 15 publications

(1 citation statement)

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“…Interpenetrating diamondoid networks occur for [Ag(dinitrile) 2 ] + complexes with ligands 1,4-butanedinitrile (succinonitrile), 1,6-hexanedinitrile (adiponitrile), 1,10-decanedinitrile (sebacodinitrile), and 1,12-dodecanedinitrile . The anion appears to have little influence on the network topology with the exception of [Ag(adiponitrile) 2 ](ClO 4 ), which has a 2D square structure, and sebacodinitrile complexes, where 3D diamondoid, 3D SrAl 2 -type and 2D layers were observed . Diamondoid structures were only obtained when the alkane chain had an even number of carbon atoms.…”

Section: Introductionmentioning

confidence: 99%

Coordination Polymers with Carborane Anions: Silver Dinitrile Complexes

2004

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Crystalline materials have been isolated and characterized from mixing the silver carborane salts Ag(CB(11)H(12)) or Ag[Co(C(2)B(9)H(11))(2)] with nitrile ligands, either terminal acetonitrile or potentially bridging alkanedinitriles. Most of the complexes showed B-H...Ag interactions between the silver center and carborane anion. [Ag(acetonitrile)(2)(CB(11)H(12))] has a hexagonal network structure. [Ag(malonitrile)(2)(CB(11)H(12))] is a discrete dimeric complex, while [Ag(4)(succinonitrile)(5)(CB(11)H(12))(4)], [Ag(glutaronitrile)(2)][Co(C(2)B(9)H(12))(2)], and [Ag(glutaronitrile)[Co(C(2)B(9)H(11))(2)]] all show coordination chain structures. The carborane anions in [Ag(adiponitrile)[Co(C(2)B(9)H(11))(2)]] bridge between Ag centers to give a 3D CdSO(4)-related coordination polymer. The structure of [Ag(malonitrile)(2)](BF(4)) was also determined to have an unusual chiral diamondoid structure with a skewed 2-fold interpenetration.

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Section: Introductionmentioning

confidence: 99%

Coordination Polymers with Carborane Anions: Silver Dinitrile Complexes

2004

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ChemInform Abstract: KRISTALL‐ UND MOLEKULARSTRUKTUR VON SILBERPERCHLORAT‐2‐ADIPINSAEUREDINITRIL

Barnhart¹,

Caughlan²,

Mazhar-Ul-Haque³

1970

Chemischer Informationsdienst. Organische Chemie

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Synthesis and Characterization of Energetic 1,2‐Bis(Oxyamino)Ethane Salts

Hawkins

Hall

Tollison

et al. 2006

Propellants Explo Pyrotec

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The synthesis, characterization, theoretical calculations, and safety studies of energetic salts based on 1,2-bis(oxyamino)ethane, (H 2 NÀOÀCH 2 ÀCH 2 ÀOÀNH 2 ), were carried out. The salts were characterized by vibrational (infrared, Raman), multinuclear NMR studies ( 1 H, 13 C), differential scanning calorimetry (DSC), elemental analysis, and initial safety testing (impact and friction sensitivity). Single crystal X-ray diffraction studies were carried out on the mono-perchlorate and the double nitrate salts, revealing the expected structures.

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Crystal and molecular structure of silver perchlorate-adiponitrile (AgClO4.2NC(CH2)4CN)

Cited by 15 publications

References 0 publications

Coordination Polymers with Carborane Anions: Silver Dinitrile Complexes

Coordination Polymers with Carborane Anions: Silver Dinitrile Complexes

ChemInform Abstract: KRISTALL‐ UND MOLEKULARSTRUKTUR VON SILBERPERCHLORAT‐2‐ADIPINSAEUREDINITRIL

Synthesis and Characterization of Energetic 1,2‐Bis(Oxyamino)Ethane Salts

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