The astrophysics and the particle physics of solar neutrinos can be tested independently by two line signals induced by neutral (NC) and charged current (CO neutrino reactions on ^Li, in a highresolution, bolometric, 4-ton LiF detector. The NC 7-ray line signal measures the flux of neutrinos of all flavors with £'v> 0.478 MeV, setting a firm empirical basis for the model-dependent links of the solar reaction chains. The CC signal from the model-independent '"pep'" line is a "yes/no" signal for flavor conservation. The shape of the CCipep) line is a direct thermometric probe of the solar core.PACS numbers: 96.60. Kx, 25.30.Pt, 95.55.Vj The unresolved status of the solar neutrino problem despite data from four major experiments strongly encourages the development of detectors with which the underlying astrophysics and particle physics can be tested independently.In this spirit, we explore a new directcounting approach based on low-energy neutral (NC) and charged current (CC) transitions in ^Li [1], which promise information of unique importance because of their low transition thresholds and the basic difference in their flavor sensitivity. The NC channel in ^Li detects neutrinos of all flavors from all the major modeldependent solar reactions, thus providing a global test of astrophysical models of the Sun. The CC channel in ^Li is tuned only to electron neutrinos (v^) from the basic p-\-e-\-p reaction in the Sun, which produces a modelindependent, monoenergetic, ''standard" flux ideal for a basic general test of nonstandard neutrino models.In the proposed experiment, the two reactions produce sharp line signals, a feature of key importance for signal identification above background. Timely developments in cryogenic bolometry which demonstrate the feasibility of keV-class energy resolution in LiF crystals [2] offer a matching high-resolution detection technique. Preliminary signal/background considerations given here show that a relatively small 4-ton solar detector may yield decisive data in one year. A LiF detector will focus on three major results: the NC and the CC line signal rates and the line shape profile of the CC signal. We outline below the significance of these objectives and broadly identify basic design criteria for a LiF detector.The CC reaction Ve -^ ^Li-> e ~ 4-''Be produces e ~ signals reflecting the solar Ve spectrum. The only line signal (at 0.580 MeV) arises from the 1.442 MeV v^ line from the solar pep reaction, a simple variant of the basic pp reaction. The Ve (pep) flux at the Sun is determined (±5%) by basic nuclear physics [3], not by the astrophysical model details. Observation of a smaller CCipep) signal at the Earth can be caused only by nonconservation of Ve flavor by various means, especially conversion in solar matter or vacuum to another (active or sterile) flavor. In the parameter spaces currently allowed by experiment, all the proposed nonstandard neutrino models predict a zero or severely reduced Ve (pep) flux at the Earth. Thus, the CC(pep) line signal in ^Li is a unique "yes...