“…WRF‐Chem tropospheric NO 2 column concentrations, or VCDs, are quantified using the averaging kernels (AKs) and the ratio of total to tropospheric air mass factors (AMFs) associated with the TROPOMI NO 2 column retrieval for each overpass (Douros et al.,
2023). This accounts for instrument sensitivity in modeled columns, creating a more direct comparison with the TROPOMI product (e.g., Poraicu et al.,
2023). The AKs and AMFs are derived from the a priori NO 2 profile from the TM5‐MP chemical transport model (Williams et al.,
2017):
where AMF and AMF trop are the TROPOMI‐provided total and tropospheric air mass factors (AMFs), respectively, A v is Avogadro's number, g is the force due to gravity, M is the molecular weight of air, n is the WRF model layer, and n tot is the total number of model layers within the troposphere, with the tropopause determined by the last model layer with a temperature lapse rate >2 C km −1 .…”