We employ the holographic quench technique to drive Einstein-Maxwell-scalar (EMs) black holes out of equilibrium and study the real-time dynamics therein. From the fully nonlinear dynamical simulations, a dynamically unstable Reissner-Nordström anti-de Sitter (RN-AdS) black hole can be scalarized spontaneously after an arbitrarily small quench. On the other hand, a dynamically stable scalarized black hole can be descalarized after a quench of sufficient strength. Interestingly, on the way to descalarization, the scalarized black hole behaves like a holographic superfluid, undergoing a dynamical transition from oscillatory to non-oscillatory decay. Such behaviors are related to the spectrums of quasi-normal modes of scalarized black holes, where the dominant mode migrates toward the imaginary axis with increasing quench strength. In addition, due to the ℤ2-symmetry preserved by the model, the ground state is degenerate. We find that there exists a threshold for the quench strength that induces a dynamical transition of the gravitational system from one degenerate ground state to the other. Near the threshold, the gravitational system is attracted to an excited state, that is, a RN-AdS black hole with dynamical instability.