2007
DOI: 10.1063/1.2713867
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Criterion for predicting the glass-forming ability of alloys

Abstract: Mechanical alloying ͑MA͒ of blended elemental powder mixtures of Fe 42 Zr 10 X 28 B 20 ͑X = Al, Co, Ge, Mn, Ni, and Sn͒ was carried out to determine their glass-forming ability ͑GFA͒ ͑as determined by the time required to form the amorphous phase͒. During milling, amorphization was achieved in systems with X = Al, Ge, or Ni, but not in the other systems. The GFA could be correlated with the total number of intermetallics present in the constituent binary phase diagrams. Thus, this work offers the equilibrium p… Show more

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Cited by 49 publications
(24 citation statements)
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References 22 publications
(15 reference statements)
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“…6b. It is worth mentioning that, in a very recent work, Sharma and Suryanarayana reported a change in the homogenization trend of some Fe based alloys for long milling times [26] (after being mechanically amorphized, mechanical crystallization is observed), which could also be responsible for the changes observed at long milling times in this work. Fig.…”
Section: Powder Particle Size and Compositionmentioning
confidence: 81%
“…6b. It is worth mentioning that, in a very recent work, Sharma and Suryanarayana reported a change in the homogenization trend of some Fe based alloys for long milling times [26] (after being mechanically amorphized, mechanical crystallization is observed), which could also be responsible for the changes observed at long milling times in this work. Fig.…”
Section: Powder Particle Size and Compositionmentioning
confidence: 81%
“…Table 4 presents the results obtained, including the equilibrium number of intermetallic phases present between X and the constituent elements (Zr, Fe or B) in the powder bend. 168,169 A close examination of Table 4 clearly reveals that the ease of amorphisation (i.e. GFA) increased with the number of intermetallics present in the constituent Zr-X binary phase diagrams.…”
Section: Inoue Criteriamentioning
confidence: 99%
“…A systematic and comprehensive investigation has recently been reported on the glass formation behaviour and stability of several Febased glassy alloys processed by MA. 168 Based on a systematic and comprehensive investigation on Fe-based alloys of the generic composition of Fe 42 X 28 Zr 10 B 20 (where the subscripts represent the composition of the alloy in atomic percentage and X5Al, Co, Ge, Mn, Ni or Sn), it was noted that amorphisation had occurred only in some alloy systems and not in all. For example, amorphisation occurred only in alloy systems with X5Al, Ge or Ni, as evidenced by the presence of a broad diffuse peak centred at the (110) Fe position in the X-ray diffraction (XRD) patterns (Fig.…”
Section: Inoue Criteriamentioning
confidence: 99%
“…5(b)), no evident morphology is seen. This is not surprising, since Ge is a known glass-former 17,35 . For the NbC film with highest Nb content in series S3 (Fig.…”
Section: Resultsmentioning
confidence: 99%