Cr(VI) anion-imprinted polymer synthesized on mesoporous silicon via synergistic action of bifunctional monomers for precise identification and separation of Cr(VI) from aqueous solution by fixed-bed adsorption

Abstract

The novel Cr(VI) anion-imprinted polymer(Cr(VI)-IIP) was prepared by a surface imprinting technique with bifunctional monomers pre-assembly system based on mesoporous silicon (SBA-15). The synthesized Cr(VI)-IIP was characterized by Fourier transmission infrared spectra (FT-IR), EDS, scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray powder diffractometer, N2 adsorption–desorption and thermogravimetric analysis (TGA), proving to be with a highly ordered mesoporous structure, as well as favorable thermal stability. The absorption characteristic of Cr(VI)-IIP followed the Langmuir adsorption isotherm model and the saturated adsorption amount was 96.32 mg/g at 25 °C – 2.7 times higher than that of non-imprinted polymer (NIP). Kinetic experiments showed that the adsorption behavior of Cr(VI)-IIP was in accordance with the pseudo-second-order kinetic model and reached the adsorption equilibrium state within 70 min. In addition, in the selectivity experiments, Cr(VI)-IIP exhibited strong specific recognition ability for Cr(VI) and could realize the separation of Cr(VI) and Cr(III) from an aqueous solution. The dynamic adsorption experiments exhibited that the dynamic adsorption efficiency of Cr(VI)-IIP was as high as 71.57%. Meanwhile, the dynamic regeneration experiments showed that the adsorption amount of Cr(VI)-IIP did not decrease significantly after repeating for five times. All of the findings suggested that Cr(VI)-IIP could achieve precise identification as well as efficient separation of Cr(VI) from aqueous solution.

Polymeric Materials in Speciation Analysis Based on Solid-Phase Extraction

“…Under the optimal conditions, Cr(III) was absorbed quantitatively, but Cr(VI) was not retained. A novel Cr(VI)-IIP was synthesized on the surface of mesoporous silicon (SBA-15) using MAA and 4-VP as bifunctional monomers and Cr(VI) anion as template ion by surface thermal initiation imprinting technique [ 127 ]. Cr(VI)-IIP prepared possesses a strong selective adsorption ability for Cr(VI) in the presence of competing ions such as Cr(III), Cu(II), Cd(II) and Ni(II), which demonstrated that Cr(VI)-IIP could be applied in complex aqueous environments to achieve efficient separation of Cr(VI) while enabling the separation of different valence states of elemental Cr.…”