Cr₂O₃ Promoted In₂O₃ Catalysts for CO₂ Hydrogenation to Methanol

Abstract

Cr2O3 was applied to study the modification of In2O3 based catalysts for CO2 hydrogenation to methanol reaction. Combined with X‐ray diffraction (XRD), scanning transmission electron microscopy (STEM), X‐ray photoelectron spectroscopy (XPS), etc., the structure of the catalysts was characterized. The reaction performances for CO2 hydrogenation to methanol were evaluated on a stainless steel fix‐bed reactor. The results showed that solid solutions were formed for the Cr2O3 promoted In2O3 catalysts. The important role of electronic interaction between Cr2O3 and In2O3 was revealed in the hydrogenation reaction. In1.25Cr0.75O3 sample exhibited the highest methanol yield, which was 2.8 times than that of pure In2O3. No deactivation was observed for In1.25Cr0.75O3 sample during the 50 h reaction. The improved catalytic performance may due to the formation of the solid solutions and the highest amount of oxygen vacancies.