Covalent triazine-based frameworks confining cobalt single atoms for photocatalytic CO2 reduction and hydrogen production

Single-Atom Pd Catalysts Supported on Covalent Triazine Frameworks for Hydrogen Production from Formic Acid

“…Covalent triazine frameworks (CTF) and their derivatives could be a good choice as supports for single-atom metal sites like it was shown for Rh, Pt, , Pd, Ru, Ni, Co, , and Ir . These materials are stable at high temperatures (>673 K).…”

Recent advances and future perspectives in MOF-derived single-atom catalysts and their application: a review

“…However, the establishment of efficient catalytic systems needs to be put on the agenda. Recently, some scholars 221 realized CO 2 reduction and hydrogen production with SACs prepared from triazinyl covalent frameworks (CTFs), which has solved some difficulties for photocatalysis. Currently, MOF-derived SACs are considered as potential CO 2 RR photocatalysts due to their maximum atomic efficiency and the advantage of MOFs in collecting sunlight.…”

Recent advances in high-crystalline conjugated organic polymeric materials for photocatalytic CO2conversion

“…The introduction of Co single atoms not only enhanced the adsorption of CO 2 , but also accelerated the separation and transfer of photocarriers, thereby promoting the photocatalytic performance. 135 Shen and co-workers reported a one-step method for the synthesis of single-atom molten Co salt coordinated with a crystalline g-C 3 N 4 /PTI heterojunction based on the built-in electric field in a homogeneous junction, which facilitates charge separation and single-atom loading for accelerating surface catalytic kinetics. The WT-EXAFS (Fig.…”