Magneto Raman scattering study of the E2g optical phonons in multi-layer epitaxial graphene grown on a carbon face of SiC are presented. At 4.2K in magnetic field up to 33 T, we observe a series of well pronounced avoided crossings each time the optically active inter Landau level transition is tuned in resonance with the E2g phonon excitation (at 196 meV). The width of the phonon Raman scattering response also shows pronounced variations and is enhanced in conditions of resonance. The experimental results are well reproduced by a model that gives directly the strength of the electron-phonon interaction.PACS numbers: 73.22. Lp, 63.20.Kr, 78.30.Na, Lattice vibrations in solids can be effectively modified via their coupling to electronic excitations, as, for example, evidenced by observations of Kohn anomalies in metals [1,2], of coupled phonon-plasmon modes in polar semiconductors [3,4] or of different phonon spectra in metallic and semiconducting carbon-nanotubes [5]. The electron-phonon interaction is currently intensively studied in graphene [6,7,8,9] which is a two-dimensional crystal of carbon atoms arranged in a honeycomb lattice and a semimetal with characteristic dispersions of electronic states displaying Dirac cones near the Fermi energy [10,11]. The case of the long wavelength optical E 2g -phonons at the Γ-point of the Brillouin zone, which corresponds to the relative displacement of two nonequivalent carbon atoms in the unit cell of graphene [6,7], is of particular interest. The perturbation due to this displacement is effective in inducing the direct (∆k = 0) electronic transitions across the Dirac point: E 2g -phonons efficiently couple to those low energy interband excitations [6,7] that are unique to graphene. The spectrum of these excitations (its 2E F low energy onset) can be modified by tuning the Fermi energy E F . This was achieved in gated graphene flakes on Si/SiO 2 substrates where the electrically modified E 2g -phonon spectrum was traced with Raman scattering methods [8,9].The spectrum of the graphene E 2g -phonon is expected to be even more severely modified by applying a magnetic field perpendicular to the 2D plane [12,13], i.e., when a continuous spectrum of electronic excitations is transformed into a series of quasi-discrete inter Landau level excitations characteristic of a 2D system. In conditions of Landau quantization, the electron phonon coupling has a resonant character which is expected between the E 2g -phonon and properly selected inter-Landau level excitations. The observation of the effects of magneto-resonant electron-phonon coupling in graphene structures, which we present in this letter, has been an experimental challenge [27] aiming at verification of theoretical predictions [12,13] and eventual confirmation of the conclusions drawn from zero-field measurements [8,9].We report here on magneto-Raman scattering studies of the E 2g -phonon band of multilayer epitaxial graphene on the carbon face of a SiC substrate (MEG), in fields up to 33 T, and low, liquid helium temp...