“…Such models have also been used to predict mineral precipitation rates in geochemical modeling studies (e.g. Steefel and MacQuarrie, 1996;Knauss et al, 2005;Steefel and Maher, 2009;Zhu, 2009;Goddéris et al, 2010;Zhu et al, 2010;Liu et al, 2011), yet the applicability of such models has not been verified in detail and may be inconsistent with what is known about mineral precipitation kinetics (e.g. Nielsen, 1964Nielsen, , 1984Nancollas and Reddy, 1971;Reddy and Nancollas, 1976;Reddy and Gaillard, 1981;Inskeep and Bloom, 1985;Mucci, 1986;Van Cappellen and Berner, 1991;Piana et al, 2006;Kowacz et al, 2007;Vekilov, 2007;Bénézeth et al, 2008;Kowacz and Putnis, 2008;Perdikouri et al, 2009;Vavouraki et al, 2010;RodriguezBlanco et al, 2011).…”