Counterion Effects in [Ru(bpy)3](X)2-Photocatalyzed Energy Transfer Reactions
Juliette Zanzi,
Zachary Pastorel,
Carine Duhayon
et al.
Abstract:Photocatalysis that uses the energy of light to promote chemical transformations by exploiting the reactivity of excited-state molecules is at the heart of a virtuous dynamic within the chemical community. Visible-light metal-based photosensitizers are most prominent in organic synthesis, thanks to their versatile ligand structure tunability allowing to adjust photocatalytic properties toward specific applications. Nevertheless, a large majority of these photocatalysts are cationic species whose counterion eff… Show more
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