Could oxalate‐extractable phosphorus replace phosphorus fractionation schemes in soil phosphorus prospections?—A case study in the prehistoric Milseburg hillfort (Germany)

Abstract

A geoarchaeological soil phosphorus (P) prospection is used to identify a gate within the prehistoric rampart of the Milseburg hillfort (Hesse, Germany). This study compares the application of a P fractionation scheme and P extraction with ammonium‐oxalate. We hypothesized that oxalate‐extractable P (P‐ox) and the related degree of P saturation (DPS) could replace the more expensive and time‐consuming fractionation schemes for geoarchaeological investigations. Comparing the results, the P fractionation helped to verify the existence of another section of the prehistoric ramparts and to identify the location of a gate within it. It also helped to discover the archaeologically relevant soil depths in the investigated area. This information could not be retrieved from the P‐ox data alone. Soil P‐ox contents and DPS values are relatively unspecific with regard to prehistoric land use. However, DPS at least indicates settled versus unsettled areas. Still, the results of the P fractionation more clearly delineate Iron Age land use areas including settlement, non‐settlement, rampart, and rampart gap (probable gate). Thus, in geoarchaeological contexts, this method seems to be preferable to a singular P‐ox extraction. However, for better results, P‐ox determination could be integrated into a P fractionation scheme.

Autogenous Eutrophication, Anthropogenic Eutrophication, and Climate Change: Insights from the Antrift Reservoir (Hesse, Germany)

“…We used three aliquots of each sediment sample for a P fractionation. We determined the following: (1) easily soluble P with 0.1 M hydrochloric acid (P dHCl ) [56]); (2) pedogenic oxide-bound P soluble in an ammonium oxalate-oxalic acid solution (P ox ; DIN 19684-6:1997-12 [56]); and (3) pseudo-total P (P AR ) after extraction with aqua regia (12.1 M HCl and 14.4 M HNO 3 in a ratio of 1:3; [56]). P dHCl was measured on the spectrophotometer according to Murphy and Riley (1962) [48].…”