2002
DOI: 10.1179/026708401225002785
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Corrosion Resistance of Conversion Film Formed on Aluminium Alloy Using Cerium Salt Surface Treatment

Abstract: Non-chromate conversion films are formed on the surface of an Al-Z n-Mg-Cu alloy using a two step cerium salt treatment. The corrosion resistance of the alloy in chloride solution has been studied after the non-chromate treatment. It was found that the conversion film could greatly improve the corrosion resistance of the alloy to pitting and uniform corrosion in a chloride environment. The non-chromate film can retard both the anodic and cathodic processes. The treated alloy is not sensitive to the changes in … Show more

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Cited by 17 publications
(9 citation statements)
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“…It was widely recognized as an attractive alternative to chromate conversion coating for the protection of aluminum alloys because cerium compounds are non-toxic and relatively cheap. Corrosion inhibition by cerium salts is generally associ- ated with the formation and precipitation of cerium oxides or hydroxides over cathodic sites [10,16,18,19]. It is a hot point for the study of Ce conversion coating on the aluminum alloy or AMCs surfaces in the corrosion research field; unfortunately, a little work has been reported on Gr-f/Al composites surface [20].…”
Section: Introductionmentioning
confidence: 99%
“…It was widely recognized as an attractive alternative to chromate conversion coating for the protection of aluminum alloys because cerium compounds are non-toxic and relatively cheap. Corrosion inhibition by cerium salts is generally associ- ated with the formation and precipitation of cerium oxides or hydroxides over cathodic sites [10,16,18,19]. It is a hot point for the study of Ce conversion coating on the aluminum alloy or AMCs surfaces in the corrosion research field; unfortunately, a little work has been reported on Gr-f/Al composites surface [20].…”
Section: Introductionmentioning
confidence: 99%
“…The magnification morphology of Ce-sealed Ni-P coating Journal of Materials Engineering and Performance the reported spectra (Ref 20,23,25). Characteristic peaks of corresponding Ce 3+ state were lacking on it.…”
mentioning
confidence: 94%
“…However, one must note that the efficiency of the various processes using cerium salts is developed. In a series of papers (Ref [21][22][23], several researchers demonstrated that treatments with aqueous solution of rare earth salts, especially cerium salts effectively inhibited the metals corrosion. These studies revealed that corrosion protection can be attributed to the formation of a hydrate rare earth oxide film over the cathodic sites on the metal surface.…”
Section: Introductionmentioning
confidence: 99%
“…A necessidade de encontrar um substituto a altura para os pré-tratamentos de superfície à base de cromato tem levado os pesquisadores a associarem diferentes tratamentos dando origem a sistemas em multicamadas. Estudos empregando sistemas em bi-camada foram pesquisados porXingwen et al (2000; eZhang et al 2002 com camadas de conversão de Ce, obtidas a partir de tratamentos químicos em duas soluções com composições distintas Xingwen et al (2000;. produziram uma bi-camada através da imersão sucessiva de uma liga Al 2024 em soluções de Ce(NO 3 ) 3 e de Ce(CO 3 ) 2 .…”
unclassified
“…Ambos os banhos foram acelerados com H 2 O 2 , acidificados com H 3 BO 3 , e o tempo de imersão da amostra em cada uma das soluções foi de 2 horas. Por EIS os autores observaram uma sensível melhora do comportamento anticorrosivo do sistema em bi-camada, caracterizado por uma impedância cerca de uma ordem de grandeza maior quando comparadas aos mesmos sistemas em monocamada Zhang et al (2002). publicaram resultados sobre a obtenção de bi-camadas de conversão de Ce sobre ligas Al-Zn-Mg-Cu por imersão sucessiva da liga em uma solução alcalina contendo sal de Ce (III), seguida da imersão em outra solução alcalina contendo um sal de Ce(IV), tratamento este denominado pelos autores como ZW.…”
unclassified