2012
DOI: 10.1179/1743278212y.0000000011
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Corrosion of steel in lithium bromide solution containing inhibitor

Abstract: The corrosion behaviour of carbon steel in 55% lithium bromide solution containing a complex organophosphonate-molybdate inhibitor has been studied using weight loss tests, electrochemical measurements, SEM and X-ray photoelectron spectroscopy. The results showed that the species provides an excellent inhibition performance in 55% lithium bromide solution. When its concentration reached 0?8 kg m 23 in 55% lithium bromidez0?07 mol dm 23 lithium hydroxide at 240uC, the carbon steel's corrosion rate decreased to … Show more

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Cited by 3 publications
(3 citation statements)
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“…However, special care should be taken when the operating temperature is above 165°C. Additionally, in a more recent work [75] showed the effectiveness of Po-Mo (an organophosphonate plus Sodium Molybdate) as a corrosion inhibitor in 55 % Lithium Bromide at 240°C, with maximum corrosion rates as low as 25 µm/year. Figure 7 illustrates the data measured by the Japan Gas Association at three different locations of the generator model test sections (see figure 7(b)): (1) transfer tube, (2) separator clearance, and (3) separator welding.…”
Section: Corrosionmentioning
confidence: 99%
“…However, special care should be taken when the operating temperature is above 165°C. Additionally, in a more recent work [75] showed the effectiveness of Po-Mo (an organophosphonate plus Sodium Molybdate) as a corrosion inhibitor in 55 % Lithium Bromide at 240°C, with maximum corrosion rates as low as 25 µm/year. Figure 7 illustrates the data measured by the Japan Gas Association at three different locations of the generator model test sections (see figure 7(b)): (1) transfer tube, (2) separator clearance, and (3) separator welding.…”
Section: Corrosionmentioning
confidence: 99%
“…Fe is often used as the material for the pipes conducting the flow and heat exchange of the LiBr solution. However, Fe usage has three drawbacks: the corrosion by aqueous Br – of Fe, pipe blockage by LiBr crystal deposition at low temperatures, and high flow resistance to highly concentrated, high-viscosity LiBr solutions . Some preventative measures such as anticorrosion additives or crystallization inhibitors have been adopted, but these methods may increase operating costs and environmental risk.…”
Section: Introductionmentioning
confidence: 99%
“…However, Fe usage has three drawbacks: the corrosion by aqueous Br − of Fe, 22 pipe blockage by LiBr crystal deposition at low temperatures, 23 and high flow resistance to highly concentrated, high-viscosity LiBr solutions. 24 Some preventative measures such as anticorrosion additives 22 or crystallization inhibitors 25 have been adopted, but these methods may increase operating costs and environmental risk. Since superhydrophobic surfaces can effectively realize anticorrosivity, drag reduction, and scaling resistance simultaneously, the application of such a functionalized surface to Fe could solve these three problems simultaneously.…”
Section: Introductionmentioning
confidence: 99%