Corrosion mitigation for steel in acid environment using novel p-phenylenediamine and benzidine coumarin derivatives: synthesis, electrochemical, computational and SRB biological resistivity
Abstract:Three novel p-phenylenediamine and benzidine coumarin derivatives were synthetized (PhODB), (BODB) and (DODB), these compounds showed excellent anti corrosion effect for steel in 1.0 M HCl and significant SRB resistance.
“…These findings suggest that SRB can reduce corrosion formation, indicating that the inhibitor compounds TODB and DODB have good biological activity against SRB. 65 …”
Two azo derivatives (TODB) and (DODB) were synthesized and characterized as mild steel (MS) corrosion inhibitors in 1 M HCl. Electrochemical data suggest that TODB and DODB are excellent inhibitors. They show anti-bacterial effect against SRB.
“…These findings suggest that SRB can reduce corrosion formation, indicating that the inhibitor compounds TODB and DODB have good biological activity against SRB. 65 …”
Two azo derivatives (TODB) and (DODB) were synthesized and characterized as mild steel (MS) corrosion inhibitors in 1 M HCl. Electrochemical data suggest that TODB and DODB are excellent inhibitors. They show anti-bacterial effect against SRB.
“…This adsorption process includes the formation of a protective barrier layer over the metal surface, which shields it from aggressive components. 70 Fig. 15 shows the adsorption modes of p -TSAH and p -TSAE in order to inhibit the mild steel corrosion in a hydrochloric acid solution.…”
Two new corrosion inhibitors were synthesized and applied to steel in 1.0 M HCl. The corrosion resistance was probed by electrochemical and theoretical methods. The study reveals significant intersections between electrochemical aspects and theory.
“…Table 5 lists the EIS parameters obtained by fitting the experimental EIS graphs to the chosen equivalent circuit. C dl is related to the CPE constants ( Y o and n ) by the equation: 53 C dl = [ Y R 1− n ct ] 1/ n …”
Two Co(ii) and Cr(iii) complexes were synthesized, characterized and examined as corrosion inhibitors. The electrochemical data showed high inhibition efficiencies with mixed-type behavior. FMO and NBO were considered for the computational analysis.
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