Corrosion inhibition of mild steel using poly (2-ethyl -2-oxazoline) in 0.1M HCl solution

Abstract

Effective inhibition of metallic corrosion to prevent its consequent loss is one of the serious apprehensions for industries in the modern world. This paper analyses the application of poly(2-ethyl-2-oxazoline) (PEOX) as an effective inhibitor of corrosion, when it is made to be in contact with the surfaces of mild steel (MS). The sustainability of MS against corrosion in 0.1 M Hydrochloric acid solution in the presence of known concentration of PEOX is assessed by potentiodynamic polarization (PDP) measurements, linear polarization studies (LPR), and electrochemical impedance spectroscopy (EIS). It was observed that PEOX behaves as better inhibitor for mild steel corrosion in 0.1 M HCl solution and it show enhanced inhibition efficiency (IE%) 79% at a concentration of 50 ppm. The polarization experiments indicated that addition of PEOX in concentrations varies from 25 ppm to 50 ppm induces a decrease of both cathodic and anodic currents densities. Also, the micrographs recorded by the Scanning Electron Microscopy confirm that molecules of PEOX act as corrosion inhibitors for the surfaces of MS in 0.1 M HCl. The stability of the MS surface in a corrosion-prone environment is traced by measuring the contact angles of water droplets placed on the MS surface, to quantify the extent of deterioration, if any, due to corrosion. The results presented here show that the compound PEOX performs as a mixed-type inhibitor against corrosion at the MS surface in acidic medium. Theoretical studies based on the electronic structure of PEOX in aqueous medium also support its performance as a successful corrosion-inhibitor.

Aspartame as a Green and Effective Corrosion Inhibitor for T95 Carbon Steel in 15 wt.% HCl Solution

“…The acceptable corrosion inhibition mechanism by organic inhibitors is the adsorption mechanism, whereby an organic molecule substitutes an adsorbed water molecule on a metal surface to form a protective film that decreases the rate at which corrosive species attack the surface [48,49]. It has already been established that the surface of carbon steel is positively charged in a highly concentrated HCl medium [36,50,51].…”

Cysteine as an Eco-Friendly Anticorrosion Inhibitor for Mild Steel in Various Acidic Solutions: Electrochemical, Adsorption, Surface Analysis, and Quantum Chemical Calculations

“…Despite this, there is not any proof in the literature that it influences inhibitory efficacy . If Δ N is smaller than 3.6, it is believed that the metal surface’s electronic inhibitor will boost the effectiveness of the inhibition . The ability of an electron to bind Cys.…”

“… 95 If Δ N is smaller than 3.6, it is believed that the metal surface’s electronic inhibitor will boost the effectiveness of the inhibition. 96 The ability of an electron to bind Cys. is known as electronegativity (χ).…”

Inhibition performance of halogen-substituted benzaldehyde thiosemicarbazones as corrosion inhibitors for mild steel in hydrochloric acid solution

“…The inhibition efficiency ( η T %) was obtained via eqn (4) and also presented. 38,39 η T % = (1 − i inhi corr / i 0 corr ) × 100%where i 0 corr and i inhi corr represent the corrosion current densities for the corrosion of mild steel in 1.0 M hydrochloric acid solution without and with different concentrations of benzaldehyde thiosemicarbazone derivatives, respectively.…”