Corrosion evolution of UNS C90300 bronze in simulated acid rain of Hong Kong

Abstract

Funding information China Overseas Building Construction LimitedCorrosion evolutions of UNS C90300 bronzes with and without artificial patina were investigated in the simulated acid rain of Hong Kong. The corrosion products mainly composed of cuprite were formed on the surface exhibiting slight protection for the bronze substrate. The ratios of Sn and Zn in the corrosion products are lower than in the alloy. The artificial patina effectively enhances the corrosion resistance of bronze substrate, even after 30 days of immersion. For both bare and patinated bronzes the Sn-and Zn-based species are absent in the outer layers of corrosion products, and Cu 2 O species in the outer layer can partially transform into Cu (II) ionic state due to the abundant supply of dissolved oxygen.

Study on Softening Resistance of Cu-Sn-Fe-P alloy for Advanced Electrical Connectors

“…Moreover, in case of the higher content of Sn in the tin-phosphorous bronze alloy, Sn is easy to form segregation in the process of casting, so only the process of horizontal continuous casting + homogenizing annealing can be used in the production generally, resulting in low production efficiency and yield. Therefore, the present study proposes how to maintain the original properties of the tin-phosphorous bronze alloy while reducing the content of the tin, and achieving the more effective industrialized production [6][7][8][9][10] .…”