The effect of phase transformation on the corrosion behaviour of Zn-22AI (wt-%) alloys immersed in NaCI solution (3-5 wt-%) at room temperature was investigated. As cast Zn-22AI alloys were isothermally heated at 300 and 250°C (the eutectoid point is 277°C) respectively and then cooled by various rates. Isothermally heated below the eutectoid point, the corrosion resistance of the alloys increased with the decreasing cooling rate. However, when the isothermal heating temperature was above the eutectoid point, the corrosion resistance of Zn-22AI alloys increased with the increasing cooling rate. It can be attributed to the existence of 0.2 phase, which may lead to smaller potential difference between the microgalvanic cells.
Experimental
Materials and heat treatmentThe Zn-22A1 specimens were prepared by melting the corresponding amounts of Zn (99-99' V() purity) and Al (99-90% purity) in a medium frequency induction melting furnace. The ingots were obtained by casting the melt into a steel mold.After casting, the specimens were subjected to two groups of heat treatments. The first group was isothermally heated at 300°C for 10 h and then cooled by