“…Owing to the ability to take part in a wide range of organic reactions and easy accessibility through nitro‐ aldol condensation, nitroalkenes have been used to synthesize a number of heterocycles such as furan,,, imidazole, pyridine, pyrimidine, indole, imidazopyridine,,, etc –. Notably, nitroalkene is bielectrophilic in nature and could serve as potential precursor to form heterocycles by reacting with binucleophiles via cascade hetero‐Michael addition reaction .…”