Corrigendum to “Palladium Complexes of Azomethine Derivatives of Porphyrins as Potential Photosensitizers” [Macroheterocycles 2015, 8(4), 376-383; DOI: 10.6060/mhc151199z]

Tyurin, V. S.; Erzina, Dina R.; Zamilatskov, Ilya A.; Chernyadyev, Andrey Yu.; Ponomarev, G. V.; Yashunskiy, D.V.; Maksimova, A.V.; Neverov, K.V.; Kozlov, A. S.; Krasnovsky, А.А.; Tsivadze, A. Yu.

doi:10.6060/mhc161073k

Cited by 2 publications

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“…[34] Target Schiff bases have the similar polarity with the compound (21), so their chromatographic separation was failed. In the case of the Ni(II) complex, the target products porphyrin gave by-product (21) with 30 % yield in addition to the target Schiff base.…”

Section: Preparation Of Azomethine Derivatives Of Pd(ii) and Ni(ii) Cmentioning

confidence: 99%

“…[33,34] There are two approaches to the synthesis of Schiff bases: the reaction of formylporphyrin with amines and the interaction of the so called "phosphorus complex" with amines. [33,34] There are two approaches to the synthesis of Schiff bases: the reaction of formylporphyrin with amines and the interaction of the so called "phosphorus complex" with amines.…”

Section: Introductionmentioning

confidence: 99%

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Transformations of meso‐Iminofunctionalized Pd(II) and Ni(II)‐Complexes of β‐Alkylsubstituted Porphyrins

et al. 2019

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The meso‐imino derivatives of the palladium (II) and nickel (II) complexes of coproporphyrins I and II and β‐octaethylporphyrin were obtained by the Vilsmeier formylation followed by interaction with amines. The metal complexes of the azomethines obtained were transformed to the corresponding complexes of cyclopentane and cyclopentane‐pyrrolidone fused porphyrin derivatives by thermolysis. The plausible mechanism of such transformations was suggested and substantiated with quantum chemical calculations. Meso‐cyano‐, meso‐hydroxy‐, and meso‐aminocarbonyl derivatives of β‐octaethylporphyrin were obtained by treatment of the corresponding meso‐imino derivatives with bases. Demetalation of the nickel complex of the meso‐ hydroxy‐β‐octaethylporphyrin led to formation of the free base derivative. The structures of new types of the porphyrin derivatives were determined via X‐ray powder diffraction analysis. The obtained types of porphyrins are promising candidates to use as photosensitizers in medicine applications due to their longer wave absorption combined with high stability.

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Section: Preparation Of Azomethine Derivatives Of Pd(ii) and Ni(ii) Cmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Transformations of meso‐Iminofunctionalized Pd(II) and Ni(II)‐Complexes of β‐Alkylsubstituted Porphyrins

et al. 2019

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Temperature dependent steric hindrance effects in triplet state relaxation of meso-phenyl-substituted Pd-octaethylporphyrins

Gorski

Knyukshto

Zenkevich

et al. 2018

Journal of Photochemistry and Photobiology A: Chemistry

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Corrigendum to “Palladium Complexes of Azomethine Derivatives of Porphyrins as Potential Photosensitizers” [Macroheterocycles 2015, 8(4), 376-383; DOI: 10.6060/mhc151199z]

Cited by 2 publications

References 0 publications

Transformations of meso‐Iminofunctionalized Pd(II) and Ni(II)‐Complexes of β‐Alkylsubstituted Porphyrins

Transformations of meso‐Iminofunctionalized Pd(II) and Ni(II)‐Complexes of β‐Alkylsubstituted Porphyrins

Temperature dependent steric hindrance effects in triplet state relaxation of meso-phenyl-substituted Pd-octaethylporphyrins

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