In this study, mesoporous TiO 2 films were formed on ITO conductive glasses by anodizing of titanium thin films without post-annealing. The titanium thin films, ~200 nm thick, sputter-deposited on to the ITO substrates were anodized at 20 V in a phosphate/glycerol electrolyte at 433 K. A completely transparent TiO 2 specimen was obtained by anodizing for 60 s. The as-anodized mesoporous TiO 2 films consisted of anatase, even without post annealing. The transparent mesoporous TiO 2 film anodized for a suitable time showed much better photoelectrochemical performance than the post-annealed TiO 2 nanotubular film.