“…The reaction between Me 2 NC 6 H 4 SiH 3 and Co 2 (CO) 8 in toluene is clearly different from that of other RSiH 3 since the solution turns distinctly purple, in contrast to the more usual orange-brown. Work-up required chromatographic separation, which led to extensive decomposition on the column so material recovery was relatively low.…”
Section: Resultsmentioning
confidence: 83%
“…pMe 2 NC 6 H 4 SiCl 3 was prepared by combining the Grignard reagent from p-Me 2 NC 6 H 4 Br with excess SiCl 4 , and reducing the chloride with LiAlH 4 gave the silane [8].…”
Section: Generalmentioning
confidence: 99%
“…The reaction of organosilanes with Co 2 (CO) 8 has long been known to give products with Si-Co bonds [1]. Thus Cl 3 SiH gives Cl 3 SiCo(CO) 4 [2], SiH 4 gives Si[Co 2 (CO) 7 ] 2 [3], and PhSiH 3 results in PhSi[Co(CO) 4 ][Co 2 (CO) 7 ] which decarbonylates to the closocluster PhSiCo 3 (CO) 9 [4].…”
Section: Introductionmentioning
confidence: 99%
“…Thus Cl 3 SiH gives Cl 3 SiCo(CO) 4 [2], SiH 4 gives Si[Co 2 (CO) 7 ] 2 [3], and PhSiH 3 results in PhSi[Co(CO) 4 ][Co 2 (CO) 7 ] which decarbonylates to the closocluster PhSiCo 3 (CO) 9 [4]. Reaction of silicon hydrides to give Si-Co bonds is involved in the hydrosilation of alkenes, catalysed by Co 2 (CO) 8 [5].…”
Section: Introductionmentioning
confidence: 99%
“…To see if there was a more specific route to these by-products we reacted p-Me 2 NC 6 H 4 SiH 3 with Co 2 (CO) 8 and now report that a completely different reaction takes place.…”
“…The reaction between Me 2 NC 6 H 4 SiH 3 and Co 2 (CO) 8 in toluene is clearly different from that of other RSiH 3 since the solution turns distinctly purple, in contrast to the more usual orange-brown. Work-up required chromatographic separation, which led to extensive decomposition on the column so material recovery was relatively low.…”
Section: Resultsmentioning
confidence: 83%
“…pMe 2 NC 6 H 4 SiCl 3 was prepared by combining the Grignard reagent from p-Me 2 NC 6 H 4 Br with excess SiCl 4 , and reducing the chloride with LiAlH 4 gave the silane [8].…”
Section: Generalmentioning
confidence: 99%
“…The reaction of organosilanes with Co 2 (CO) 8 has long been known to give products with Si-Co bonds [1]. Thus Cl 3 SiH gives Cl 3 SiCo(CO) 4 [2], SiH 4 gives Si[Co 2 (CO) 7 ] 2 [3], and PhSiH 3 results in PhSi[Co(CO) 4 ][Co 2 (CO) 7 ] which decarbonylates to the closocluster PhSiCo 3 (CO) 9 [4].…”
Section: Introductionmentioning
confidence: 99%
“…Thus Cl 3 SiH gives Cl 3 SiCo(CO) 4 [2], SiH 4 gives Si[Co 2 (CO) 7 ] 2 [3], and PhSiH 3 results in PhSi[Co(CO) 4 ][Co 2 (CO) 7 ] which decarbonylates to the closocluster PhSiCo 3 (CO) 9 [4]. Reaction of silicon hydrides to give Si-Co bonds is involved in the hydrosilation of alkenes, catalysed by Co 2 (CO) 8 [5].…”
Section: Introductionmentioning
confidence: 99%
“…To see if there was a more specific route to these by-products we reacted p-Me 2 NC 6 H 4 SiH 3 with Co 2 (CO) 8 and now report that a completely different reaction takes place.…”
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.