In this paper, we consider a stationary heat problem on a twocomponent domain with an ε-periodic imperfect interface, on which the heat flux is proportional via a nonlinear function to the jump of the solution, and depends on a real parameter γ. Homogenization and corrector results for the corresponding linear case have been proved in Donato et al. (J Math Sci 176(6):891-927, 2011), by adapting the periodic unfolding method [see (Cioranescu et al. SIAM J Math Anal 40(4):1585-1620, 2008), (Cioranescu et al. SIAM J Math Anal 44(2):718-760, 2012), (Cioranescu et al. Asymptot Anal 53 (4): 2007)] to the case of a twocomponent domain. Here, we first prove, under natural growth assumptions on the nonlinearities, the existence and the uniqueness of a solution of the problem. Then, we study, using the periodic unfolding method, its asymptotic behavior when ε → 0. In order to describe the homogenized problem, we complete some convergence results of Donato et al. (J Math Sci 176(6):891-927, 2011) concerning the unfolding operators and we investigate the limit behaviour of the unfolded Nemytskii operators associated to the nonlinear terms. According to the values of the parameter γ we have different limit problems, for the cases γ < −1, γ = −1 and γ ∈ ]−1, 1]. The most relevant case is γ = −1, where the homogenized matrix differs from that of the linear case, and is described in a more complicated way, via a nonlinear function involving the correctors.Mathematics Subject Classification. 35B27, 35J65, 82B24.