“…Indeed, each family of molecules that we and others have explored has displayed diverse reactivity. For instance, 1-aryl cyclohept-1-enes undergo thermal [2 + 2] reactions, 16 while benzofused cycloheptenes undergo facile [3 + 2] reactions with dipoles such as azides. 12,17 More recently, we and others have seen that highly strained trans-cyclohexenes 18 also offer attractive synthetic opportunities.…”
Herein, we investigate the use of visible light to indirectly drive ring opening in unstrained 6- and 7-membered ring systems via reaction with a transiently generated trans-cycloalkene. Identification of conditions...
“…Indeed, each family of molecules that we and others have explored has displayed diverse reactivity. For instance, 1-aryl cyclohept-1-enes undergo thermal [2 + 2] reactions, 16 while benzofused cycloheptenes undergo facile [3 + 2] reactions with dipoles such as azides. 12,17 More recently, we and others have seen that highly strained trans-cyclohexenes 18 also offer attractive synthetic opportunities.…”
Herein, we investigate the use of visible light to indirectly drive ring opening in unstrained 6- and 7-membered ring systems via reaction with a transiently generated trans-cycloalkene. Identification of conditions...
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